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Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents

  • 64-19-7

  • Industrial Grade; Food Grade

  • C2H4O2; CH3COOH

  • 60.052 g/mol

  • 2915211900

  • Acetic acid

  • Acetic acid glacial; Glacial acetic acid; Ethanoic acid; Ethylic acid; Hydrogen acetate; Methanecarboxylic acid

Availability:

1. Package information

30kg/HDPE drum---800drums/20fcl*---24mts*/20fcl

220kg/HDPE drum---80drums/20fcl---17.6mts/20fcl

1.05mts/IBC drum---20drums/20fcl---21mts/20fcl


*20fcl=20 feet container load

*mts=metric tons

2. Product Summary

Name: Glacial Acetic Acid

Grade: Industrial Grade; Food Grade

Content: 80%, 90%, 99.8%, 99.9%


2.1 Identifiers

IUPAC Name

Acetic acid

Synonyms

Acetic acid glacial; Glacial acetic acid; Ethanoic acid; Ethylic acid; Hydrogen acetate; Methanecarboxylic acid

Molecular formula

C2H4O2; CH3COOH

Molecular weight

60.05 g/mol

CAS No.

64-19-7

InChI

InChI=1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)

SMILES

CC(O)=O

ChemSpider

171

ChEMBL

ChEMBL539

ECHA InfoCard

100.000.528

EC Number

200-580-7

PubChem CID

176

UNII

Q40Q9N063P

UN Code

2789

HS Code

2915211900


2.2 Physical and chemical Properties

Physical State

Liquid

Appearance

Colorless

Odor

pungent

Odor Threshold

No information available

pH

2.4 at 60.05 g/mol

Melting Point/Range

16.2°C - lit.

Boiling Point/Range

117°C - 118°C

Flash Point

No information available

Evaporation Rate

No information available

Flammability (solid, gas)

Not applicable

Upper Flammability or explosive limits

Upper explosion limit: 19.9% (V)

Lower Flammability or explosive limits

Lower explosion limit: 4% (V)

Vapor Pressure

73.3 hPa at 50.0°C

15.2 hPa at 20.0°C

Vapor Density

No information available

Relative Density

1.049 g/cm3 at 25°C

Solubility

Completely soluble

Partition coefficient (n-octanol/water)

logPow: -0.17

Autoignition Temperature

485.0°C

Decomposition Temperature

No information available

Viscosity

No information available


2.3 Spectral information

No data available


2.4 Safety and Hazards information

2.4.1 Classification

OSHA/HCS status     

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 3

SKIN CORROSION - Category 1A

SERIOUS EYE DAMAGE - Category 1

 

2.4.2 GHS label elements 

Hazard pictograms

Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents

Signal word  

Danger

Hazard statements

Flammable liquid and vapor.

Causes severe skin burns and eye damage.

 

2.4.3 Precautionary statements

Prevention

Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting, and all material-handling equipment. Do not breathe vapor or spray. Wear protective gloves. Wear eye or face protection. Wear protective clothing.

Response

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Storage  

Not applicable.

Disposal 

Dispose of contents and container in accordance with all local, regional, national, and international regulations.

Supplemental label elements 

Not applicable.

Hazards not otherwise classified  

Corrosive to respiratory tract

2.5 Stability and reactivity

 Reactivity

 No data available.

 Chemical stability

 Stable under recommended storage conditions.

 Possibility of hazardous reactions

 No data available

 Conditions to avoid  

 Heat, flames, and sparks.

 Incompatible materials   

 Oxidizing agents, Soluble carbonates and phosphates, Hydroxides, Metals, Peroxides, permanganates, for   example potassium permanganate, Amines, Alcohols, Nitric acid

 Hazardous decomposition products     

 Hazardous decomposition products formed under fire conditions.-Carbon oxides

 Other decomposition products-No data available


2.6 Toxicological information

2.6.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - 3.310 mg/kg

Remarks: (RTECS)

LC50 Inhalation - Mouse - 4 h - 2.819 mg/l

Remarks: (RTECS)

Skin corrosion/irritation

Skin - Rabbit

Result: Causes burns. - 4 h

(OECD Test Guideline 404)

Remarks: (IUCLID)

Serious eye damage/eye irritation

Eyes - Rabbit

Result: Causes burns. - 4 h

(OECD Test Guideline 405)

Remarks: (IUCLID)

Causes serious eye damage.

Respiratory or skin sensitization

No data available

Germ cell mutagenicity

Ames test

Salmonella typhimurium

Result: negative

Mutagenicity (mammal cell test): chromosome aberration.

Chinese hamster ovary cells

Result: negative

Mutagenicity (micronucleus test)

Rat - male and female - Bone marrow

Result: negative

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is

identified as probable, possible, or confirmed human carcinogen by IARC.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Additional Information

RTECS: AF1225000

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Ingestion or inhalation of concentrated acetic acid causes damage to tissues of the respiratory and digestive tracts. Symptoms include hematemesis, bloody diarrhea, edema and/or perforation of the esophagus and pylorus, pancreatitis, hematuria, anuria, uremia, albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, cardiovascular collapse, shock, and death. Direct contact or exposure to high concentrations of vapor with skin or eyes can cause erythema, blisters, tissue destruction with slow healing, skin blackening, hyperkeratosis, fissures, corneal erosion, opacification, iritis, conjunctivitis, and possible blindness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


2.7 Ecological information

2.7.1 Toxicity

Toxicity   to fish

semi-static   test LC50 - Oncorhynchus mykiss (rainbow trout) - >

1.000   mg/l - 96 h (OECD Test Guideline 203)

Toxicity   to daphnia and other aquatic invertebrates

static   test EC50 - Daphnia magna (Water flea) - > 1.000 mg/l - 48 h

(OECD   Test Guideline 202)

Toxicity   to algae

static   test EC50 - Skeletonema costatum - > 1.000 mg/l - 72 h

(ISO   10253)

Toxicity   to bacteria

EC5   - Pseudomonas putida - 2.850 mg/l - 16 h

Remarks:   neutral (maximum permissible toxic concentration) (Lit.)

microtox   test EC50 - Photobacterium phosphoreum - 11 mg/l - 15

min

Remarks:   (IUCLID)

2.7.2 Persistence and degradability

Biodegradability

Result:   99 % - Readily biodegradable.

(OECD   Test Guideline 301D)

Remarks:   (HSDB)

Result:   95 % - Readily eliminated from water

(OECD   Test Guideline 302B)

Biochemical   Oxygen

Demand   (BOD)

880   mg/g

Remarks:   (Lit.)

Ratio   BOD/ThBOD

76   %

Remarks:   (IUCLID)

2.7.3 Bioaccumulative potential

No data available

2.7.4 Mobility in soil

No data available

2.7.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

2.7.6 Other adverse effects

Additional   ecological

Information

No   data available



Useage


Acetic acid also called ethanoic acid, is the most important of the carboxylic acids. Organic glacial acetic acid has a variety of uses in different industrial areas, one of the most common usage is in the form of household vinegar, which generally containing 5% of acetic acid and 95% of water. Generally, non aqueous glacial acetic acid has two major area of application, Industrial and food. When acetic acid is at 99.5 percent concentration, it is referred to as glacial acetic acid. Glacial acetic acid has a variety of uses, including as a raw material and solvent in the production of other chemical products.

 

Industrial applications for glacial acetic acid include:  


Vinyl Acetate, cellulose fibers, and plastics: Acetic acid is used to make many chemicals, including vinyl acetate, acetic anhydride, and acetate esters. Vinyl acetate is used to make polyvinyl acetate, a polymer used in paints, adhesives, plastics, and textile finishes.

Acetic anhydride is used in the manufacture of cellulose acetate fibers and plastics used for photographic film, clothing, and coatings.

Acetic acid is also used in the chemical reaction to produce purified terephthalic acid (PTA), which is used to manufacture the PET plastic resin used in synthetic fibers, food containers, beverage bottles and plastic films.

Solvents: Acetic acid is a hydrophilic solvent, like ethanol. It dissolves compounds such as oils, sulfur and iodine and mixes with water, chloroform, and hexane.

Acidizing oil and gas: Acetic acid can help reduce metal corrosion and scale build-up in oil and gas well applications. It is also used in oil well stimulation to improve flow and increase production of oil and gas.

Pharmaceuticals and vitamins: The pharmaceutical industry uses acetic acid in the manufacture of vitamins, antibiotics, hormones, and other products.

Other uses: Salts of acetic acid and various rubber and photographic chemicals are made from acetic acid. Acetic acid and its sodium salt are commonly used as a food preservative.

 

Non aqueous glacial acetic acid for flavoring agents in food industrial:


Glacial acetic acid for flavoring agents can use to preparation vinegar, which is a common food ingredient, often used as a brine in pickling liquids, vinaigrettes, marinades, and other salad dressings. Organic glacial acetic acid for flavoring agents also can be used in food preparation to help control Salmonella contamination in meat and poultry products.

Cleaning: organic non aqueous glacial acetic acid can be used throughout the home as a window cleaner, to clean automatic coffee makers and dishes, as a rinsing agent for dishwashers, and to clean bathroom tile and grout. Organic non aqueous glacial acetic acid for flavoring agents can also be used to clean food-related tools and equipment because it generally does not leave behind a harmful residue and requires less rinsing.

Gardening: In concentrations of 10 to 20 percent, acetic acid can be used as a weed killer on gardens and lawns. When used as an herbicide, the acetic acid can kill weeds that have emerged from the soil, but does not affect the roots of the weed, so they can regrow.

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Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents

Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents

Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents

Non Aqueous Organic Glacial Acetic Acid For Flavoring Agents


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